Main Conference Day 2

Day 3

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Oral lipid-based formulations are attracting considerable attention due to their capacity to facilitate gastrointestinal absorption and reduce or eliminate the effect of food on the absorption of poorly water-soluble, lipophilic drugs. Despite the obvious and demonstrated utility of these formulations for addressing a persistent and growing problem of major significance, the pharmaceutical industry has been slow to apply and further develop this technology. This presentation will expound on:
  • Leading technologies in the solubility space
  • Maximizing your resources to ensure you are getting the most impact from the methods you are currently employing
David Hauss
Principal
Hauss Associates

9:15 AM Case Study: Approaches to Leverage In-Vitro Data to Hypothesize In-Vivo Data

Jennifer Sheng , Scientific Technical Leader, Sandoz

It can often be the case that a compound is more soluble in-vitro, when all the variables are carefully controlled, than actually in the human body. The variable between “in-vitro” solubility and “in-vivo” solubility exists, but is rarely discussed. This session will delve into:
  • A unique case study illustrating the problem
  • Techniques to hypothesize in-vivo data from in-vitro analysis
  • Overcoming hurdles to in-vivo solubility
Jennifer Sheng
Scientific Technical Leader
Sandoz

Accurate predictions of human pharmacokinetic and pharmacodynamic (PK/PD) profiles are critical in early drug development, as safe, efficacious, and “developable” dosing regimens of promising compounds have to be identified. While advantages of successful integration of preclinical PK/PD data in the “anticipation” of human doses (AHD) have been recognized, pharmaceutical scientists have faced difficulties with practical implementation, especially for PK/PD profile projections of compounds with challenging absorption, distribution, metabolism, excretion and formulation properties. This session will explore:
Practical projection approaches for formulation-dependent human PK/PD parameters and profiles of Biopharmaceutics Classification System classes I-IV drugs based on preclinical data are described
  • Case examples for “AHD” demonstrate the utility of preclinical and clinical PK/PD modeling for formulation risk identification, lead candidate differentiation, and prediction of clinical outcome
  • Methods to enhance prediction confidence such as in vitro–in vivo extrapolations in clearance predictions using in vitro microsomal data are discussed
  • Examples for integration of clinical PK/PD and formulation data from frontrunner compounds via “reverse pharmacology strategies” that minimize uncertainty with PK/PD predictions are included
Tycho Heimbach
Senior Investigator II
Novartis

11:30 AM Influence of Particle Size on the Ultraviolet Spectrum of Particulate-Containing Solutions

David Alonso , Senior Research Scientist, Abbott Laboratories

Determination of solution concentration, particularly within the framework of dissolution testing, is an important technique in the evaluation of drug products, both during formulation development and as a quality control tool. Traditionally, quantification of the dissolved drug concentration in the dissolution medium as a function of time is performed by removing samples from the dissolution vessel followed by filtration and subsequent ultraviolet (UV) or high performance liquid chromatography combined with UV analysis (HPLC-UV). An increasingly important alternative to these traditional techniques is the in situ measurement of dissolution profiles using fiber-optic UV/ Vis probes. This session covers: 
  • The effect of UV waves on solubility, for both large and small particles
  • Concentration determination in applications such as the miniaturized analysis of (intrinsic) dissolution rates using a rotating disk or powder
  • Estimations of particle sizes based on dissolution rate data
  • Determination of precipitation behavior in artificial stomach-duodenum models
David Alonso
Senior Research Scientist
Abbott Laboratories

12:15 PM Networking Lunch

1:15 PM Hot Melt Extrusion as Formulation Enabling Technology in Early to Clinical Stage Development

Anjali Agrawal , Principal Research Scientist, Boehringer Ingelheim Pharmaceuticals

Hot Melt Extrusion (HME) has been the hottest technology in solubility for a few years now. This session will present a case study on how to implement HME as well as benchmarks, hard metrics to measure success. The case study will illustrate:
  • Formulation component selection approaches for HME
  • Miniaturization and small scale assessment of HME process
  • In vitro and in vivo performance assessment of HME dispersion
  • Scale up aspects of HME process
Anjali Agrawal
Principal Research Scientist
Boehringer Ingelheim Pharmaceuticals

2:00 PM Stability Prediction for Amorphous Materials

Sunny Bhardwaj , Senior Scientist, Merck

The pharmaceutical community is increasing its attention on the amorphous state of numerous pharmaceuticals wherein the crystalline state, in light of the poor aqueous solubility, will not deliver the desired drug concentration into the systemic circulation. However, the amorphous state can confer both physical and chemical instability. The effective use of these amorphous compounds requires the ability to predict their stability. The overall objective of this case study is to:
  • Build correlation models which can be used to predict the stability of amorphous materials
  • Evaluate the relationship between different molecular motions and various important properties related to the stability of amorphous pharmaceuticals including crystallization and water sorption
Sunny Bhardwaj
Senior Scientist
Merck

3:30 PM Co-Crystal Development: From Mortar & Pestle to Production

Peter Karapinski , Principal Fellow, Novartis

The need for selecting an optimal, soluble form of active pharmaceutical ingredient (API), the regulatory mandates, and the growing cost of drug development compel pharmaceutical companies to perform exhaustive study prior to the selection of the final API form.  Cocrystals offer a viable alternative to salts, and may be a form of choice for neutral APIs. There are more cocrystal formers than salt forming agents, which necessitates automated screening techniques. This talk focuses on the use of particle engineering in order to:
  • Obtain the correct polymorph of your co-crystal
  • Ensure high co-crystal purity level
  • Maximize co-crystal yield
  • Manipulate particle size of co-crystal
  • Avoid milling and possible amorphization of co-crystal
  • Case study examples will elucidate the particle engineering methodology applied to co-crystallization
Peter Karapinski
Principal Fellow
Novartis

There are two emerging techniques showing promise in the field of nanocrystal techniques. Nanococrystals combines nanoparticle engineering and crystal engineering for the formulation of nanoparticles. Conventional nanocrystals technology usually focuses on improving the dissolution rate to enhance bioavailability. Amorphous nanoparticle engineering has also been studied to increase API concentration. However, the use of nanoparticles of the amorphous drug in the formulation needs to overcome the challenge in stabilizing the amorphous form during both manufacture and the shelf life of the drug product. Nanococrystal application can potentially increase API concentration without creating disadvantages in the stability and powder properties of the amorphous form. This session covers:
  • A case study of an emerging application to the nanocystals technique is the layer-by-layer coating technique applied to nanoparticles
  • Exploring if coated nanoparticles will not only improve particle stability as well as  offer the possibility of designing nanoparticle surfaces that can achieve controlled release and targeted delivery
Dedong Wu
Senior Research Scientist
AstraZeneca

Among different strategies to enhance bioavailability of poorly water-soluble drugs, amorphous solid dispersions have received much interest due to the higher solubility of amorphous API compared to its crystalline counterpart. Given the meta-stable nature of amorphous substances, the polymer matrix in which API is dispersed must then play several important roles to ensure such solubility benefit. This talk will be discussing: 1) in solid state, how the polymer of choice should help overcome the physical stability challenge by preventing, thermodynamically and/or kinetically, the crystallization tendency of the amorphous API; and more importantly 2) during dissolution, how the polymer’s surface properties and solution behavior affect the release of API. Observations will be compared between commonly used polymers such as HPMC, PVP and PVPVA with well-studied model drugs as well as developmental drugs.
Jing Tao
Research Investigator
Bristol-Myers Squibb

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